Jada Pinkett Smith with the 'Oprah's Big Give' contestants

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After the meeting with Gayle, Nate tells the contestants that even more star power is on the way. Actress Jada Pinkett Smith—a generous giver and the wife of actor Will Smith— wants to help.

The contestants meet Jada and fill her in on their mission. Immediately, she promises that the Smith Family Foundation will make a generous donation. Then she begins working the phones.

"We got $100,000 in 10 minutes," Cameron says. "Now that's star power."