Brad Pitt and Cate Blanchett

When people found out that Brad and Cate were going to be on The Oprah Winfrey Show, our e-mail in-boxes were flooded with burning questions from fans around the country.

Jennifer and her husband, Michael, are Skyping in from Homer Glen, Illinois, with a question for Brad. Has Brad ever been left home alone in charge of all six children? "And how have you handled it?" Jennifer asks.

Brad considers himself to be the disciplinarian in the family but hasn't been left alone with all six children. "Four is usually my limit on my own, so far," Brad says. "I hope to advance to six."