Working on the spot in the sinewy web between the thumb and forefinger, called Meeting Mountains, can help relieve headaches, Fuenmayor says. Start with your left hand palm down. Place four right-hand fingers under the web and the thumb on top. Apply pressure, gently squeezing the web, then make a circular motion with the thumb, rubbing the whole area for five to ten seconds. Wait for a count of five, and repeat. Then switch hands.